Trimethylsilyl iodide iodotrimethylsilane or tmsi is an organosilicon compound with the chemical formula ch 3 3 sii. Thus, in the presence of 1, the following conversions are reported to occur efficiently and under mild conditions. In the reaction of trimethylsilyl iodide with esters the silyl group acts as an activating lewis acid, while the iodine attacks as the nucleophile. Observation by flow 1h nmr and dimerization kinetics and. Chemical properties of iodotrimethylsilane cas 16029984 download as pdf file download as excel file download as 2d mole file predict properties. Based solid acid as a new catalyst in heterogeneous mixtures. Buy trimethylsilyl trifluoromethanesulfonate cas 27607778, a strong silylating agent, from santa cruz.
It is a colorless, volatile liquid at room temperature. Buy trimethyl2trimethylsilylmethylbenzylammonium iodide cas 83781479, a product for proteomics research, from santa cruz. Media in category trimethylsilyl iodide the following 4 files are in this category, out of 4 total. Structure, properties, spectra, suppliers and links for.
Articles of trimethylsilyl iodide are included as well. Find support for a specific problem on the support section of our website. In particular the use of trimethylsilyl iodide, silyloxydienes, and vinyl iodides are highlighted, several structural organosilicon studies are. A convenient in situ preparation of trimethylsilyl iodide. View enhanced pdf access article on wiley online library html view download pdf for offline viewing. This is an open access article distributed under the creative. The use of organosilicon compounds in synthesis is described. Abstract the ability of trimethylsilyl iodide 1 to effect a variety of useful synthetic transformations has been amply demonstrated. Trimethylsilyl iodide 16029984 pricing, chemical properties, structure, cas number, molecular formula. Search results for trimethylsilyl iodide at sigmaaldrich. Trimethylsilyl iodide may be prepared by the oxidative cleavage of hexamethyldisilane by iodine or by the cleavage of hexamethyldisiloxane with aluminium. Trimethylsilyl iodide an overview sciencedirect topics. Efficiency conversion of trimethylsilyl ethers to their corresponding ethers using carbon. Trimethyl2trimethylsilylmethylbenzylammonium iodide.
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